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AIIMS 2004
Exam
AIIMS
Year
2004
Subject
Chemistry
Chapter
Coordination Compounds

AIIMS 2004 · Chemistry · Coordination Compounds

Assertion : The [Ni( en )_3] Cl_2 (en = ethylene diamine) has lower...

Assertion : The [Ni( en )3]Cl2\left[\mathrm{Ni}(\text{ en })_3\right] \mathrm{Cl}_2 (en = ethylene diamine) has lower stability than \left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_2.Reason:In[Ni(en)3]Cl2. Reason : In \left[\mathrm{Ni}(\mathrm{en})_3\right] \mathrm{Cl}_2 the geometry of Ni\mathrm{Ni} is trigonal bipyramidal.

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of assertion
  2. BIf both assertion and reason are true but reason is not the correct explanation of assertion
  3. CIf assertion is true but reason is false
  4. DIf both assertion and reason are false.

Correct answer

D. If both assertion and reason are false.

Step-by-step solution

[Ni(en)3]Cl2\left[\mathrm{Ni}(\mathrm{en})_3\right] \mathrm{Cl}_2 is a chelating compound and chelated complexes are more stable than similar complexes with unidentate ligands as dissociation of the complex involves breaking of two bonds rather than one. In [Ni(en)3]Cl2,Ni\left[\mathrm{Ni}(\mathrm{en})_3\right] \mathrm{Cl}_2, \mathrm{Ni} with d8d^8 configuration shows octahedral geometry. Six electrons will occupy the t2gt_{2 g} orbitals and two electrons will occupy the ege_g orbitals.
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