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JEE Main
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Chemistry
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Solid State

JEE Main · Chemistry · Solid State

An ionic compound MX crystallizes in a rock-salt lattice. The molar...

An ionic compound MX crystallizes in a rock-salt lattice. The molar mass of the compound is 48 g mol−148\text{ g mol}^{-1} and its density is 5.0 g cm−35.0\text{ g cm}^{-3}. The shortest distance between two M+\text{M}^+ ions in the lattice is x2×10−10x\sqrt{2} \times 10^{-10} m. The value of xx is _________.
(Given : NA=6.0×1023 mol−1N_A = 6.0 \times 10^{23}\text{ mol}^{-1})

Correct answer

2

Step-by-step solution

For a rock-salt (NaCl type) lattice, the effective number of formula units per unit cell is Z=4Z = 4.

Using the density formula:
d=Z×MNA×a3d = \dfrac{Z \times M}{N_A \times a^3}

Substitute the given values to find the volume of the unit cell, a3a^3:
5.0=4×486.0×1023×a35.0 = \dfrac{4 \times 48}{6.0 \times 10^{23} \times a^3}

a3=19230×1023=6.4×10−23 cm3=64×10−24 cm3a^3 = \dfrac{192}{30 \times 10^{23}} = 6.4 \times 10^{-23}\text{ cm}^3 = 64 \times 10^{-24}\text{ cm}^3

Taking the cube root gives the edge length aa:
a=4×10−8 cm=4×10−10 ma = 4 \times 10^{-8}\text{ cm} = 4 \times 10^{-10}\text{ m}

In a rock-salt lattice, the cations (M+\text{M}^+) form a face-centered cubic (FCC) sub-lattice. The shortest distance between two identical ions (next-nearest neighbors) is half the face diagonal of the unit cell:
Distance = a22=a2\dfrac{a\sqrt{2}}{2} = \dfrac{a}{\sqrt{2}}

Substitute the value of aa:
Distance = 4×10−102 m=22×10−10 m\dfrac{4 \times 10^{-10}}{\sqrt{2}}\text{ m} = 2\sqrt{2} \times 10^{-10}\text{ m}

Comparing this with the given expression x2×10−10 mx\sqrt{2} \times 10^{-10}\text{ m}, we get:
x=2x = 2

Answer: 22
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