JEE Main
- Exam
- JEE Main
- Subject
- Chemistry
- Chapter
- Solid State
JEE Main · Chemistry · Solid State
An ionic compound MX crystallizes in a rock-salt lattice. The molar...
An ionic compound MX crystallizes in a rock-salt lattice. The molar mass of the compound is and its density is . The shortest distance between two ions in the lattice is m. The value of is _________.
(Given : )
(Given : )
Correct answer
2
Step-by-step solution
For a rock-salt (NaCl type) lattice, the effective number of formula units per unit cell is .
Using the density formula:
Substitute the given values to find the volume of the unit cell, :
Taking the cube root gives the edge length :
In a rock-salt lattice, the cations () form a face-centered cubic (FCC) sub-lattice. The shortest distance between two identical ions (next-nearest neighbors) is half the face diagonal of the unit cell:
Distance =
Substitute the value of :
Distance =
Comparing this with the given expression , we get:
Answer:
Using the density formula:
Substitute the given values to find the volume of the unit cell, :
Taking the cube root gives the edge length :
In a rock-salt lattice, the cations () form a face-centered cubic (FCC) sub-lattice. The shortest distance between two identical ions (next-nearest neighbors) is half the face diagonal of the unit cell:
Distance =
Substitute the value of :
Distance =
Comparing this with the given expression , we get:
Answer: