JEE Main
- Exam
- JEE Main
- Subject
- Chemistry
- Chapter
- Solid State
JEE Main · Chemistry · Solid State
A certain metal can crystallise in simple cubic (sc), body-centred...
A certain metal can crystallise in simple cubic (sc), body-centred cubic (bcc), and face-centred cubic (fcc) lattices. Assuming the atomic radius of the metal remains constant across all three forms, let , , and be the unit cell edge lengths for the sc, bcc, and fcc lattices, respectively. The value of the expression $3 \times \left( \dfrac{a_2 \cdot a_3}{a_1^2} \right)^2 is _________.
Correct answer
8
Step-by-step solution
The relationship between the edge length ra_1 = 2r\sqrt{3}a_2 = 4r \Rightarrow a_2 = \dfrac{4r}{\sqrt{3}}\sqrt{2}a_3 = 4r \Rightarrow a_3 = 2\sqrt{2}r\dfrac{a_2 \cdot a_3}{a_1^2}\dfrac{a_2 \cdot a_3}{a_1^2} = \dfrac{\left(\dfrac{4r}{\sqrt{3}}\right) \cdot (2\sqrt{2}r)}{(2r)^2}\dfrac{a_2 \cdot a_3}{a_1^2} = \dfrac{\dfrac{8\sqrt{2}r^2}{\sqrt{3}}}{4r^2} = \dfrac{2\sqrt{2}}{\sqrt{3}}
Finally, multiply by 3:
Answer:
Finally, multiply by 3:
Answer: