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JEE Main
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JEE Main
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Chemistry
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Solid State

JEE Main · Chemistry · Solid State

A certain metal can crystallise in simple cubic (sc), body-centred...

A certain metal can crystallise in simple cubic (sc), body-centred cubic (bcc), and face-centred cubic (fcc) lattices. Assuming the atomic radius rr of the metal remains constant across all three forms, let a1a_1, a2a_2, and a3a_3 be the unit cell edge lengths for the sc, bcc, and fcc lattices, respectively. The value of the expression $3 \times \left( \dfrac{a_2 \cdot a_3}{a_1^2} \right)^2 is _________.

Correct answer

8

Step-by-step solution

The relationship between the edge length aandtheatomicradiusa and the atomic radiusrforthethreecubiclatticesisasfollows:<br>Forsimplecubic(sc):for the three cubic lattices is as follows:<br>For simple cubic (sc):a_1 = 2r<br>Forbody−centredcubic(bcc):<br>For body-centred cubic (bcc):\sqrt{3}a_2 = 4r \Rightarrow a_2 = \dfrac{4r}{\sqrt{3}}<br>Forface−centredcubic(fcc):<br>For face-centred cubic (fcc):\sqrt{2}a_3 = 4r \Rightarrow a_3 = 2\sqrt{2}r<br><br>Substitutetheseintothegivenexpression<br><br>Substitute these into the given expression\dfrac{a_2 \cdot a_3}{a_1^2}:<br>:<br>\dfrac{a_2 \cdot a_3}{a_1^2} = \dfrac{\left(\dfrac{4r}{\sqrt{3}}\right) \cdot (2\sqrt{2}r)}{(2r)^2}<br><br><br><br>\dfrac{a_2 \cdot a_3}{a_1^2} = \dfrac{\dfrac{8\sqrt{2}r^2}{\sqrt{3}}}{4r^2} = \dfrac{2\sqrt{2}}{\sqrt{3}}<br><br>Now,squarethisterm:<br>(a2⋅a3a12)2=(223)2=83<br><br>Now, square this term:<br>\left( \dfrac{a_2 \cdot a_3}{a_1^2} \right)^2 = \left( \dfrac{2\sqrt{2}}{\sqrt{3}} \right)^2 = \dfrac{8}{3}

Finally, multiply by 3:
3×83=83 \times \dfrac{8}{3} = 8

Answer: 88
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