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JEE Main
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Practical Chemistry

JEE Main · Chemistry · Practical Chemistry

An unknown transition metal salt X is subjected to the borax bead...

An unknown transition metal salt XX is subjected to the borax bead test. It forms a transparent blue bead when heated in an oxidizing flame and allowed to cool. When the same bead is heated in a reducing flame and cooled, it turns opaque red.

The spin-only magnetic moment of the metal cation responsible for the blue colour in the oxidizing flame is closest to:

Options

  1. A3.87 BM3.87 \text{ BM}
  2. B0.00 BM0.00 \text{ BM}
  3. C2.83 BM2.83 \text{ BM}
  4. D1.73 BM1.73 \text{ BM}

Correct answer

D. 1.73 BM1.73 \text{ BM}

Step-by-step solution

The characteristic colour changes in the borax bead test identify the metal present in salt XX.

A blue bead in an oxidizing flame (when cold) that turns opaque red in a reducing flame (when cold) is characteristic of copper.

In the oxidizing flame, copper forms copper(II) metaborate, Cu(BO2)2\text{Cu}(\text{BO}_2)_2. The metal cation responsible for the blue colour is Cu2+\text{Cu}^{2+}.

The atomic number of copper is 2929. Its electronic configuration is [Ar]3d104s1[\text{Ar}] 3d^{10} 4s^1.
For the Cu2+\text{Cu}^{2+} ion, the electronic configuration is [Ar]3d9[\text{Ar}] 3d^9.

In the 3d93d^9 configuration, there is 11 unpaired electron (n=1n = 1).

The spin-only magnetic moment μ\mu is given by the formula:
μ=n(n+2) BM\mu = \sqrt{n(n+2)} \text{ BM}
μ=1(1+2)=3≈1.73 BM\mu = \sqrt{1(1+2)} = \sqrt{3} \approx 1.73 \text{ BM}

Answer: 1.73 BM1.73 \text{ BM}
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