JEE MainChemistryClassification of Elements and Periodicity in Properties
The correct increasing order of the second ionization enthalpies of C , N , O and F is :
Options
- AC < O < N < F
- BC < N < F < O
- CC < N < O < F
- DC < O < F < N
Correct answer
B. C < N < F < O
Step-by-step solution
Second ionization enthalpy ( IE ₂ ) is the energy required to remove an electron from the univalent gaseous cation ( M^+ ). The valence electronic configurations of the univalent cations are: C ^+ : 2s^2 2p^1 N ^+ : 2s^2 2p^2 O ^+ : 2s^2 2p^3 F ^+ : 2s^2 2p^4 The O ^+ ion has an exactly half-filled 2p^3 subshell, which imparts extra stability. Removing an electron from this stable configuration requires exceptionally high energy, making the IE ₂ of oxygen the highest among these four elements. For the remaining ion