MHT CET Medical202622 April 2026Evening ShiftChemistryCoordination CompoundsActual
Which of the following coordination compounds is not likely to show optical isomerism?
Options
- A[ NiCl ₂( en )₂]
- B[ Co(en) ₃]³⁺
- C[ Cu(NH ₃)₄]²⁺
- D[PtCl₂(en)₂]²⁺
Correct answer
C. [ Cu(NH ₃)₄]²⁺
Step-by-step solution
Optical isomerism is generally shown by octahedral complexes that lack elements of symmetry (plane of symmetry, center of symmetry). Let us analyze each complex: Option (1): [NiCl₂(en)₂] can exist in cis and trans isomeric forms. The cis form lacks a plane of symmetry and is optically active. The trans form has a plane of symmetry and is optically inactive. Therefore, the complex as a whole can show optical isomerism. Option (2): [Co(en)₃]³⁺ is an octahedral complex with three bidentate ligands. It lacks any plane