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MHT CET Medical202622 April 2026Evening ShiftChemistryCoordination CompoundsActual

Which of the following coordination compounds is not likely to show optical isomerism?

Options

  1. A[ NiCl ₂( en )₂]
  2. B[ Co(en) ₃]³⁺
  3. C[ Cu(NH ₃)₄]²⁺
  4. D[PtCl₂(en)₂]²⁺

Correct answer

C. [ Cu(NH ₃)₄]²⁺

Step-by-step solution

Optical isomerism is generally shown by octahedral complexes that lack elements of symmetry (plane of symmetry, center of symmetry). Let us analyze each complex: Option (1): [NiCl₂(en)₂] can exist in cis and trans isomeric forms. The cis form lacks a plane of symmetry and is optically active. The trans form has a plane of symmetry and is optically inactive. Therefore, the complex as a whole can show optical isomerism. Option (2): [Co(en)₃]³⁺ is an octahedral complex with three bidentate ligands. It lacks any plane

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