MHT CET 202622 AprilMorning Shift
- Exam
- MHT CET
- Year
- 2026
- Date
- 22 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Coordination Compounds
MHT CET 2026 · 22 April · Morning Shift · Chemistry · Coordination Compounds
Find the hybridization and number of coordinate bonds formed in...
Find the hybridization and number of coordinate bonds formed in tetracyanonickelate(II) ion respectively.
Options
- A and 4 coordinate bonds
- B and 4 coordinate bonds.
- C and 2 coordinate bonds
- D and 2 coordinate bonds
Correct answer
B. and 4 coordinate bonds.
Step-by-step solution
The given complex ion is tetracyanonickelate(II), which is .
The central metal ion is Ni in +2 oxidation state. The atomic number of Ni is 28, so the electronic configuration of is .
Since is a strong field ligand, it causes the pairing of the electrons. The 8 electrons pair up to occupy four orbitals, leaving one orbital empty.
The empty orbitals available for hybridization are one , one , and two orbitals. Thus, the hybridization is , resulting in a square planar geometry.
Since there are four monodentate ligands, each donates a pair of electrons to the central metal ion, forming a total of 4 coordinate bonds.
Therefore, the hybridization is and the number of coordinate bonds is 4.
Answer: and 4 coordinate bonds.
The central metal ion is Ni in +2 oxidation state. The atomic number of Ni is 28, so the electronic configuration of is .
Since is a strong field ligand, it causes the pairing of the electrons. The 8 electrons pair up to occupy four orbitals, leaving one orbital empty.
The empty orbitals available for hybridization are one , one , and two orbitals. Thus, the hybridization is , resulting in a square planar geometry.
Since there are four monodentate ligands, each donates a pair of electrons to the central metal ion, forming a total of 4 coordinate bonds.
Therefore, the hybridization is and the number of coordinate bonds is 4.
Answer: and 4 coordinate bonds.