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MHT CET 202622 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
22 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Coordination Compounds

MHT CET 2026 · 22 April · Morning Shift · Chemistry · Coordination Compounds

Find the hybridization and number of coordinate bonds formed in...

Find the hybridization and number of coordinate bonds formed in tetracyanonickelate(II) ion respectively.

Options

  1. Asp3d2sp^3d^2 and 4 coordinate bonds
  2. Bdsp2dsp^2 and 4 coordinate bonds.
  3. Cdsp2dsp^2 and 2 coordinate bonds
  4. Dsp3sp^3 and 2 coordinate bonds

Correct answer

B. dsp2dsp^2 and 4 coordinate bonds.

Step-by-step solution

The given complex ion is tetracyanonickelate(II), which is [Ni(CN)4]2−[Ni(CN)_4]^{2-}.

The central metal ion is Ni in +2 oxidation state. The atomic number of Ni is 28, so the electronic configuration of Ni2+Ni^{2+} is [Ar]3d8[Ar] 3d^8.

Since CN−CN^- is a strong field ligand, it causes the pairing of the 3d3d electrons. The 8 electrons pair up to occupy four 3d3d orbitals, leaving one 3d3d orbital empty.

The empty orbitals available for hybridization are one 3d3d, one 4s4s, and two 4p4p orbitals. Thus, the hybridization is dsp2dsp^2, resulting in a square planar geometry.

Since there are four monodentate CN−CN^- ligands, each donates a pair of electrons to the central metal ion, forming a total of 4 coordinate bonds.

Therefore, the hybridization is dsp2dsp^2 and the number of coordinate bonds is 4.

Answer: dsp2dsp^2 and 4 coordinate bonds.
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