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NEET 2011
Exam
NEET
Year
2011
Subject
Chemistry
Chapter
Coordination Compounds

NEET 2011 · Chemistry · Coordination Compounds

Of the following complex ions, which is diamagnetic in nature?

Of the following complex ions, which is diamagnetic in nature?Of the following complex ions, which is diamagnetic in nature?Of the following complex ions, which is diamagnetic in nature?

Options

  1. A[Ni(CN)4]2−\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}
  2. B[CuCl4]2−\left[\mathrm{CuCl}_4\right]^{2-}
  3. C[CoF6]3−\left[\mathrm{CoF}_6\right]^{3-}
  4. D[NiCl4]2−\left[\mathrm{NiCl}_4\right]^{2-}

Correct answer

A. [Ni(CN)4]2−\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}

Step-by-step solution

Electronic configuration of Ni2+\mathrm{Ni}^{2+} in \left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}<imgsrc="https://cdn−question−pool.getmarks.app/pyq/neet/BvlCRzhnAOgiuAzhDkPNBpUAF7pZoxk82Q77gIjUvrc.original.fullsize.png"><br><img src="https://cdn-question-pool.Quantrex.app/pyq/neet/BvlCRzhnAOgiuAzhDkPNBpUAF7pZoxk82Q77gIjUvrc.original.fullsize.png"><br>\mathrm{Ni}^{2+}hashasd s p^2hybridisation,ashybridisation, as\mathrm{CN}^{-}isastrongfieldligand.<imgsrc="https://cdn−question−pool.getmarks.app/pyq/neet/NaF8c0LTZztyyluFowWKaNsC99aGvtMUJldu5I0u1Q.original.fullsize.png"><br>is a strong field ligand.<img src="https://cdn-question-pool.Quantrex.app/pyq/neet/NaF8c0LTZztyyluFowWKaNsC99aGvtMUJldu5I0u_1Q.original.fullsize.png"><br>\therefore\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-} is diamagnetic (becasue of the absence of unpaired electrons).
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