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NEET2011ChemistryCoordination CompoundsActual

The complexes [ Co ( NH ₃ )₆ ] [ Cr ( CN )₆ ] and [ Cr ( NH ₃ )₆ ] [ Co ( CN )₆ ] are the examples of which type of isomerism?

Options

  1. AIonisation isomerism
  2. BCo-ordination isomerism
  3. CGeometrical isomerism
  4. DLinkage isomerism

Correct answer

B. Co-ordination isomerism

Step-by-step solution

The complexes [ Co ( NH ₃ )₆ ] [ Cr ( CN )₆ ] and [ Cr ( NH ₃ )₆ ] [ Co ( CN )₆ ] are the examples of co-ordination isomerisms. This isomerism occurs only in those complexes in which both cation and anion are complex. It occurs due to exchange of ligands between cation and anion.

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