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NEET 2011
Exam
NEET
Year
2011
Subject
Chemistry
Chapter
Coordination Compounds

NEET 2011 · Chemistry · Coordination Compounds

The complexes [Co(NH_3)_6][Cr(CN)_6] and [Cr (NH_3)_6][Co(CN)_6]...

The complexes [Co(NH3)6][Cr(CN)6]\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right] and \left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Co}(\mathrm{CN})_6\right] are the examples of which type of isomerism?

Options

  1. AIonisation isomerism
  2. BCo-ordination isomerism
  3. CGeometrical isomerism
  4. DLinkage isomerism

Correct answer

B. Co-ordination isomerism

Step-by-step solution

The complexes [Co(NH3)6][Cr(CN)6]\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right] and \left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Co}(\mathrm{CN})_6\right] are the examples of co-ordination isomerisms. This isomerism occurs only in those complexes in which both cation and anion are complex. It occurs due to exchange of ligands between cation and anion.
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