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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

NTA Abhyas 2020 · Chemistry · Classification of Elements and Periodicity in Properties

Which of the following orders is incorrect with respect to the...

Which of the following orders is incorrect with respect to the property indicated ?

Options

  1. ANH3<PH3<AsH3{NH}_{3} < {PH}_{3} < {AsH}_{3}& (acidic behaviour)
  2. BLi<Be<B<CLi < Be < B < C& (first ionisation energy)
  3. CAl2O3<MgO<Na2O<K2O{Al}_{2}{O}_{3} < MgO < {Na}_{2}O < {K}_{2}O& (basic character)
  4. DLi+<Na+<K+<Cs+{Li}^{+} < {Na}^{+} < K^{+} < {Cs}^{+}& (ionic radius)

Correct answer

B. Li<Be<B<CLi < Be < B < C& (first ionisation energy)

Step-by-step solution

(i) Bond angle of {\text{NH}_{3} = {107}^{o}

{\text{PH}_{3} > {\text{AsH}_{3} = {90}^{o}

According to bond angle the %s character of lp in {\text{NH}_{3} = 22% while in {\text{PH}_{3} \text{ and } {\text{AsH}_{3} having approximately 100%, so the donation of lp in {\text{PH}_{3} \text{ and } {\text{AsH}_{3} are difficult. Hence, the acidic character increases and the order of acidic character is {\text{NH}_{3} < {\text{PH}_{3} < {\text{AsH}_{3} is correct

(ii) On moving left to right in a period ionisation energy increases. Li<Be<B<CLi < Be < B < C but the first ionisation potential of BeBe is higher than that of BB because BeBe has fulfilled configuration.

(iii) Metallic character increases hence the basic character of oxide increases.

(iv) In a group from top to the bottom, the number of the shell increases hence radius increases.
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