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[ N i C l 4 ] 2 - , [ P t C l 4 ] 2 - and [ P d C l 4 ] 2 - are respectively :-

Options

  1. Ahigh spin, low spin, high spin
  2. Blow spin, low spin, low spin
  3. Chigh spin, low spin, low spin
  4. Dlow spin, high spin, high spin

Correct answer

C. high spin, low spin, low spin

Step-by-step solution

[ N i C l 4 ] 2 - → Ni is 3d series element → C l - weak ligand → High spin [ P d C l 4 ] 2 - → Pd is 4d series element → Low spin [ P t C l 4 ] 2 - → Pt is 5d series element → Cl − act as strong field ligand for Pt and Pd as they are 5d, 4d elements respectively with high effective nuclear charge.

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