NTA Abhyas JEE Main2020ChemistryCoordination CompoundsPractice
Given the molecular formula of the hexacoordinate complexes A CoCl 3 ·6 NH 3 B CoCl 3 ·5 NH 3 C CoCl 3 ·4 NH 3 If the number of coordinated NH 3 molecules in A, B and C respectively are 6, 5 and 4, the primary valency in (A), (B) and (C) are -
Options
- A3, 3, 3
- B0, 1, 2
- C3, 2, 1
- D6, 5, 4
Correct answer
A. 3, 3, 3
Step-by-step solution
Co has six coordination number, hence formulae for compounds A, B and C should be A Co NH 3 6 Cl 3 B Co NH 3 5 Cl Cl 2 NH 3 C Co NH 3 4 Cl 2 Cl NH 3 2 Primary valency is equal to the oxidation state of the central metal ion.