The major products obtained from the reactions in List-II are the...

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in List-II and choose the correct options.

	LIST - I		LIST - II
(P)	Stephen reaction	(1)	$\text{Toluene}\xrightarrow{\substack{\text{(i)}\mathrm{CrO}_2 \mathrm{Cl}_2 / \mathrm{CS}_2 \\ \text{(ii)}\mathrm{H}_3 \mathrm{O}^{+}}}$
(Q)	Sandmeyer reaction	(2)	$\text{Benzoic acid}\xrightarrow{\substack{\text{(i)}\mathrm{PCL}_5 \\ \text{(ii)}\mathrm{H}_3 \\ \text{(iii)}\mathrm{P}_4 \mathrm{O}_{10},\Delta}}$
(R)	Hoffmann bromamide degradation reaction	(3)	$\text{Nitrobenzene}\xrightarrow{$ $\begin{array}{l}\text{(i) Fe,}\mathrm{HCl}\\ \text{(ii)}\mathrm{HCl},\mathrm{NaNO}\\ (273-278 \mathrm{~K}),\mathrm{H}_2 \mathrm{O}\end{array}$ $}$
(S)	Cannizzaro reaction	(4)	$\text{Toluene}\xrightarrow{$ $\begin{array}{l}\text{(i)}\mathrm{Cl}_2 / \mathrm{hv},\mathrm{H}_2 \mathrm{O}\\ \text{(ii)}\mathrm{Tollen's}\text{reagent}\\ \text{(iii)}\mathrm{SO}_2 \mathrm{Cl}_2 \\ \text{(iv)}\mathrm{NH}_3 \end{array}$ $}$
		(5)	$\text{Aniline}\xrightarrow{$ $\begin{array}{l}\text{(i)}\left(\mathrm{CH}_3 \mathrm{CO}\right)_2 \mathrm{O},\text{Pyridine}\\ \text{(ii)}\mathrm{HNO}_3,\mathrm{H}_2 \mathrm{O}_4,288 \mathrm{~K}\\ \text{(iii) aq.}\mathrm{NaOH}\end{array}$ $}$

Options

A $\mathrm{P} \rightarrow 2 ; \mathrm{Q} \rightarrow 4 ; \mathrm{R} \rightarrow 1 ; \mathrm{S} \rightarrow 3$
B $\mathrm{P} \rightarrow 2 ; \mathrm{Q} \rightarrow 3 ; \mathrm{R} \rightarrow 4 ; \mathrm{S} \rightarrow 1$
C $\mathrm{P} \rightarrow 5 ; \mathrm{Q} \rightarrow 3 ; \mathrm{R} \rightarrow 4 ; \mathrm{S} \rightarrow 2$
D $\mathrm{P} \rightarrow 5 ; \mathrm{Q} \rightarrow 4 ; \mathrm{R} \rightarrow 2 ; \mathrm{S} \rightarrow 1$

Correct answer

B. $\mathrm{P} \rightarrow 2 ; \mathrm{Q} \rightarrow 3 ; \mathrm{R} \rightarrow 4 ; \mathrm{S} \rightarrow 1$

Step-by-step solution

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