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JEE Advanced 2011Paper 1
Exam
JEE Advanced
Year
2011
Paper
Paper 1
Subject
Chemistry
Chapter
Amines

JEE Advanced 2011 · Paper 1 · Chemistry · Amines

The major product of the following reaction is

The major product of the following reaction is The major product of the following reaction is

Options

  1. AWhat does the proportional constant (η) measure in terms of fluid properties?
  2. BWhat does the proportional constant (η) measure in terms of fluid properties?
  3. CWhat does the proportional constant (η) measure in terms of fluid properties?
  4. DWhat does the proportional constant (η) measure in terms of fluid properties?

Correct answer

A. What does the proportional constant (η) measure in terms of fluid properties?

Step-by-step solution

It is the first step of Gabriel's phthalimide synthesis. The hydrogen bonded to nitrogen is sufficiently acidic due to two α\alpha-carbonyls. The major product of the following reaction is
The conjugate base formed above act as nucleophile in the subsequent step of reaction. As shown above, the nucleophile exist in three resonating form, one may think of oxygen being the donor atom in the nucleophilic attack. However, nitrogen act as donor as it is better donor than oxygen.The major product of the following reaction is
Bromine is not substituted in the above reaction as it is in resonance with benzene ring giving partial double bond character to C−Br\mathrm{C}-\mathrm{Br} bond, hence difficult to break.The major product of the following reaction is
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