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JEE Advanced 2023Paper 1
Exam
JEE Advanced
Year
2023
Paper
Paper 1
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Advanced 2023 · Paper 1 · Chemistry · Chemical Kinetics

The plot of logk _ f versus (1)/(T) for a reversible reaction A ( g...

The plot of logkf{logk}_{f} versus 1T\dfrac{1}{T} for a reversible reaction A(g)⇌P(g)A ( g ) ⇌ P ( g ) is shown.

The plot of logk _ f versus (1)/(T) for a reversible reaction A ( g ) ⇌ P ( g ) is shown. Pre-exponential factors for

Pre-exponential factors for the forward and backward reactions are 1015s−1and1011s−1{10}^{15}{s}^{- 1} and {10}^{11}{s}^{- 1}, respectively. If the value of logKlogK for the reaction at 500K500K is 66, the value of \left|{logk}_{b}\right|atat250Kis<br/>[K=)equilibriumconstantofthereaction,kf=is<br />\left[K =\right)equilibrium constant of the reaction, {k}_{f} =rate constant of forward reaction, {K}_{b} =$rate constant of backward reaction]

Correct answer

0

Step-by-step solution

From the question
{Af=1015,Ab=1011,f=Forward reactionlogKat500K=6b=Backward reactionlogkfat500K=9(from graph)logkbat500K:logK=log⁡(kfkb)since⇒K=kfkb\begin{cases}{A}_{f} = {10}^{15}, {A}_{b} = {10}^{11}, & f = \text{Forward reaction} \\ logK\text{at}500K = 6 & b = \text{Backward reaction} \\ {logk}_{f}\text{at}500K = 9\text{(from graph)} & \\ {logk}_{b}\text{at}500K: & \\ logK = \log \left(\dfrac{{k}_{f}}{{k}_{b}}\right)\text{since} ⇒ K = \dfrac{{k}_{f}}{{k}_{b}} & \end{cases}

6=logkf−logkb6 = {logk}_{f} - {logk}_{b}

6=9−logkb6 = 9 - {logk}_{b}

logkb=3at500Klog {k}_{b} = 3\text{at}500K

logk2k1=−EaR(1T2−1T1)log \dfrac{{k}_{2}}{{k}_{1}} = \dfrac{- {E}_{a}}{R}\left(\dfrac{1}{{T}_{2}} - \dfrac{1}{{T}_{1}}\right)

kb=Abe−EabRT{k}_{b} = {A}_{b}e\dfrac{- {E}_{ab}}{RT}

lnkb=ln⁡(Abe−EabRT)ln {k}_{b} = \ln \left({A}_{b}e\dfrac{- {E}_{ab}}{RT}\right)

lnkb=lnAb−EabRT{lnk}_{b} = {lnA}_{b} - \dfrac{{E}_{ab}}{RT}

2.303logkb=2.303logAb−Eab500R2 . 303{logk}_{b} = 2 . 303{logA}_{b} - \dfrac{{E}_{ab}}{500R}

Ea500R=2.303(logAb−logkb)\dfrac{{E}_{a}}{500R} = 2 . 303\left({logA}_{b} - {logk}_{b}\right)

Ea500R=2.303(log1011−3)\dfrac{{E}_{a}}{500R} = 2 . 303\left(log{10}^{11} - 3\right)

Ea500R=2.303(11−3)=2.303×8\dfrac{{E}_{a}}{500R} = 2 . 303 ( 11 - 3 ) = 2 . 303 \times 8

Ea=2.303×8×500R{E}_{a} = 2 . 303 \times 8 \times 500R

ln⁡(k2k1)=−EaR(1T2−1T1)\ln \left(\dfrac{{k}_{2}}{{k}_{1}}\right) = \dfrac{- {E}_{a}}{R}\left(\dfrac{1}{{T}_{2}} - \dfrac{1}{{T}_{1}}\right)

ln⁡(k250Kk500K)=−EaR(1250−1500)\ln \left(\dfrac{{k}_{250K}}{{k}_{500K}}\right) = \dfrac{- {E}_{a}}{R}\left(\dfrac{1}{250} - \dfrac{1}{500}\right)

ln⁡(k250Kk500K)=−2.303×8×500RR(1500)\ln \left(\dfrac{{k}_{250K}}{{k}_{500K}}\right) = \dfrac{- 2 . 303 \times 8 \times 500R}{R}\left(\dfrac{1}{500}\right)

2.303(logk250K−logk500K)=−2.303×82 . 303\left({logk}_{250K} - {logk}_{500K}\right) = - 2 . 303 \times 8

logk250K−3=−8{logk}_{250K} - 3 = - 8

logk250K=−5{logk}_{250K} = - 5

\left|{logk}_{250K}\right| = 5

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