JEE Advanced 2023 · Paper 1 · Chemistry · Chemical Kinetics
The plot of logk _ f versus (1)/(T) for a reversible reaction A ( g...
The plot of logkf versus T1 for a reversible reaction A(g)⇌P(g) is shown.
Pre-exponential factors for the forward and backward reactions are 1015s−1and1011s−1, respectively. If the value of logK for the reaction at 500K is 6, the value of \left|{logk}_{b}\right|at250Kis<br/>[K=)equilibriumconstantofthereaction,kf=rate constant of forward reaction, {K}_{b} =$rate constant of backward reaction]
Correct answer
0
Step-by-step solution
From the question ⎩⎨⎧Af=1015,Ab=1011,logKat500K=6logkfat500K=9(from graph)logkbat500K:logK=log(kbkf)since⇒K=kbkff=Forward reactionb=Backward reaction