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JEE Advanced 2013Paper 1
Exam
JEE Advanced
Year
2013
Paper
Paper 1
Subject
Chemistry
Chapter
Coordination Compounds

JEE Advanced 2013 · Paper 1 · Chemistry · Coordination Compounds

Consider the following complex ions, P, Q and R. The correct order...

Consider the following complex ions, P, Q and R.
Consider the following complex ions, P, Q and R. The correct order of the complex ions, according to their spin-only 
The correct order of the complex ions, according to their spin-only magnetic moment values (in B.M.) is

Options

  1. AR < Q < P\text{R < Q < P}
  2. BQ < R < P\text{Q < R < P}
  3. CR < P < Q\text{R < P < Q}
  4. DQ < P < R\text{Q < P < R}

Correct answer

B. Q < R < P\text{Q < R < P}

Step-by-step solution

F−F^{-} and H2O{H}_{2} \text{O} are weak field ligands so pairing of electrons in metal cations 3d subshell will not take place.

now we have to cosider hybridization that is given in following diagram.
Consider the following complex ions, P, Q and R. The correct order of the complex ions, according to their spin-only

μP=n(n+2)n=5=5×7=35BM{μ}_{P} = \sqrt{n\left(n + 2\right)}n = 5 = \sqrt{5 \times 7} = \sqrt{35}\text{BM}


μQ=n(n+2)n=3=3×5=15BM{μ}_{Q} = \sqrt{n ( n + 2 )}n = 3 = \sqrt{3 \times 5} = \sqrt{15}\text{BM}


μR=n(n+2)n=4=4×6=24BM{μ}_{R} = \sqrt{n ( n + 2 )}n = 4 = \sqrt{4 \times 6} = \sqrt{24}\text{BM}
μQ<μR<μP{μ}_{Q} < {μ}_{R} < {μ}_{P}
Q < R < P\text{Q < R < P}

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