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JEE Advanced 2013Paper 1
Exam
JEE Advanced
Year
2013
Paper
Paper 1
Subject
Chemistry
Chapter
Coordination Compounds

JEE Advanced 2013 · Paper 1 · Chemistry · Coordination Compounds

The pair(s) of coordination complexes/ions exhibiting the same kind...

The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism is (are)

Options

  1. A\left[\text{Cr} {\left({\text{NH}}_{3}\right)}_{5} \text{Cl}\right] {\text{Cl}}_{2}and[Cr(NH3)4Cl2]Cland \left[\text{Cr} {\left({\text{NH}}_{3}\right)}_{4} {\text{Cl}}_{2}\right] \text{Cl}
  2. B[Co(NH3)4Cl2]+{\left[\text{Co} {\left({\text{NH}}_{3}\right)}_{4} {\text{Cl}}_{2}\right]}^{+} and [Pt(NH3)2(H2O)Cl]+{\left[\text{Pt} {\left({\text{NH}}_{3}\right)}_{2} \left({\text{H}}_{2} \text{O}\right) \text{Cl}\right]}^{+}
  3. C[CoBr2Cl2]2−{\left[\text{Co} {\text{Br}}_{2} {\text{Cl}}_{2}\right]}^{2 -} and [PtBr2Cl2]2−{\left[\text{Pt} {\text{Br}}_{2} {\text{Cl}}_{2}\right]}^{2 -}
  4. D\left[\text{Pt} {\left({\text{NH}}_{3}\right)}_{3} \left({\text{NO}}_{3}\right)\right] \text{Cl}and[Pt(NH3)3Cl]Brand \left[\text{Pt} {\left({\text{NH}}_{3}\right)}_{3} \text{Cl}\right] \text{Br}

Correct answer

B. [Co(NH3)4Cl2]+{\left[\text{Co} {\left({\text{NH}}_{3}\right)}_{4} {\text{Cl}}_{2}\right]}^{+} and [Pt(NH3)2(H2O)Cl]+{\left[\text{Pt} {\left({\text{NH}}_{3}\right)}_{2} \left({\text{H}}_{2} \text{O}\right) \text{Cl}\right]}^{+}

Step-by-step solution

\left[\text{Cr} {\left({\text{NH}_{3}\right)}_{5} \text{Cl}\right] {\text{Cl}_{2} and \left[\text{Cr} {\left({\text{NH}_{3}\right)}_{4} {\text{Cl}_{2}\right] \text{Cl},bothcompoundswillnotshoweitherstructuralorstereoisomerism.<br/>, both compounds will not show either structural or stereoisomerism.<br />{\left[\text{Co} {\left({\text{NH}_{3}\right)}_{4} {\text{Cl}_{2}\right]}^{+}andand{\left[\text{Pt} {\left({\text{NH}_{3}\right)}_{2} \left({\text{H}_{2} \text{O}\right) \text{Cl}\right]}^{+},Ma<sub>4</sub>b<sub>2</sub>type(octahedral),Ma<sub>2</sub>bctype(squareplanar)andbothwillshowgeometricalisomerism.<br/>, Ma<sub>4</sub>b<sub>2</sub> type (octahedral), Ma<sub>2</sub>bc type (square planar) and both will show geometrical isomerism. <br />{\left[\text{Co} {\text{Br}_{2} {\text{Cl}_{2}\right]}^{2 -}andand{\left[\text{Pt} {\text{Br}_{2} {\text{Cl}_{2}\right]}^{2 -},Ma<sub>4</sub>b<sub>2</sub>type(tetrahedral),Ma<sub>2</sub>b<sub>2</sub>(squareplanar).<br/>, Ma<sub>4</sub>b<sub>2</sub> type (tetrahedral), Ma<sub>2</sub>b<sub>2</sub> (square planar). <br />\left[\text{Pt} {\left({\text{NH}_{3}\right)}_{3} \left({\text{NO}_{3}\right)\right] \text{Cl}and \left[\text{Pt} {\left({\text{NH}_{3}\right)}_{3} \text{Cl}\right] \text{Br} both will show ionisation isomerism.
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