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JEE Advanced 2013Paper 1
Exam
JEE Advanced
Year
2013
Paper
Paper 1
Subject
Chemistry
Chapter
Coordination Compounds

JEE Advanced 2013 · Paper 1 · Chemistry · Coordination Compounds

EDTA ^ 4 - is ethylenediaminetetraacetate ion. The total number of...

EDTA4−{\text{EDTA}}^{4 -} is ethylenediaminetetraacetate ion. The total number of N - Co - O bond angles in [Co(EDTA)]1−{\left[\text{Co} \left(\text{EDTA}\right)\right]}^{1 -} complex ion isEDTA ^ 4 - is ethylenediaminetetraacetate ion. The total number of N - Co - O bond angles in [Co (EDTA)] ^ 1 - complexEDTA ^ 4 - is ethylenediaminetetraacetate ion. The total number of N - Co - O bond angles in [Co (EDTA)] ^ 1 - complex

Correct answer

8

Step-by-step solution

EDTA4−{EDTA}^{4 -} is a hexadentate ligand containing four negative charges on its corner oxygen atoms as follows :

EDTA ^ 4 - is ethylenediaminetetraacetate ion. The total number of N - Co - O bond angles in [Co (EDTA)] ^ 1 - complex

 

Being a hexadentate ligand, it forms a ring like structure through chelation.

 

 

EDTA ^ 4 - is ethylenediaminetetraacetate ion. The total number of N - Co - O bond angles in [Co (EDTA)] ^ 1 - complex

 

The central metal ion CoCo is in the centre, coordinated to the two NN atoms and the four O−{O}^{-} ions through chelation. Now, if we observe, we see that each NN atom forms four N−Co−ON - Co - O bonds with the four O−{O}^{-} ions. Therefore, two NN atoms will form 2×4=82 \times 4 = 8 N−Co−ON - Co - O bonds in the complex structure of [Co(EDTA)]1−[ Co ( EDTA ) {]}^{1 -}. Each bond will have a certain bond angle. Hence, it can be concluded that the total number of N−Co−ON - Co - O bond angles in the complex ion is 88.

 

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