JEE Main20264 April 2026Morning ShiftChemistryAminesActual
Product C of the following reaction sequence will be
Options
- A1-Bromo-4-nitrobenzene
- B1, 3, 5-Tribromo-2-nitrobenzene
- C4-Bromo-1-nitrobenzene
- D1, 3, 5-Tribromobenzene
Correct answer
B. 1, 3, 5-Tribromo-2-nitrobenzene
Step-by-step solution
Aniline on reaction with bromine water gives 2,4,6-tribromoaniline (A) as the major product due to the strong activating nature of the - NH ₂ group. Reaction of (A) with NaNO ₂/ HCl at 273-278 K (diazotization) yields 2,4,6-tribromobenzenediazonium chloride (B). Treatment of (B) with HBF ₄ forms 2,4,6-tribromobenzenediazonium fluoroborate. Heating this intermediate with NaNO ₂ and Cu replaces the diazonium group with a nitro group, forming 2,4,6-tribromonitrobenzene (C). To assign the IUPAC name, we number the ring