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JEE Main20262 April 2026Morning ShiftChemistryAminesActual

Match List - I with List - II. List - I Mixture of Compounds List - II Reagent used to distinguish A. Diethyl amine + Ethyl amine I. Bromine water B. Acetaldehyde + Acetone II. CHCl₃ + KOH, C. Ethanol + Phenol III. Neutral FeCl₃ D. Benzoic acid + Cinnamic acid IV. Ammonical silver nitrate Choose the correct answer from the options given below :

Options

  1. AA-IV, B-II, C-I, D-III
  2. BA-IV, B-II, C-III, D-I
  3. CA-II, B-IV, C-I, D-III
  4. DA-II, B-IV, C-III, D-I

Correct answer

D. A-II, B-IV, C-III, D-I

Step-by-step solution

Diethyl amine is a secondary amine and ethyl amine is a primary amine. Primary amines give the carbylamine test with CHCl₃ and KOH on heating, while secondary amines do not. Thus, A matches with II. Acetaldehyde is an aldehyde and acetone is a ketone. Aldehydes reduce ammoniacal silver nitrate (Tollens' reagent) to form a silver mirror, while ketones do not. Thus, B matches with IV. Phenol reacts with neutral FeCl₃ to form a violet-colored complex, whereas ethanol does not react. Thus, C matches with III. Cinnamic

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