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JEE Main 20262 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Amines

JEE Main 2026 · 2 April · Morning Shift · Chemistry · Amines

Match List - I with List - II. List - I Mixture of Compounds List -...

Match List - I with List - II.
List - I
Mixture of Compounds
List - II
Reagent used to distinguish
A. Diethyl amine + Ethyl amineI. Bromine water
B. Acetaldehyde + AcetoneII. CHCl3+KOH,ΔCHCl_3 + KOH, \Delta
C. Ethanol + PhenolIII. Neutral FeCl3FeCl_3
D. Benzoic acid + Cinnamic acidIV. Ammonical silver nitrate

Choose the correct answer from the options given below :

Options

  1. AA-IV, B-II, C-I, D-III
  2. BA-IV, B-II, C-III, D-I
  3. CA-II, B-IV, C-I, D-III
  4. DA-II, B-IV, C-III, D-I

Correct answer

D. A-II, B-IV, C-III, D-I

Step-by-step solution

Diethyl amine is a secondary amine and ethyl amine is a primary amine. Primary amines give the carbylamine test with CHCl3CHCl_3 and KOHKOH on heating, while secondary amines do not. Thus, A matches with II.

Acetaldehyde is an aldehyde and acetone is a ketone. Aldehydes reduce ammoniacal silver nitrate (Tollens' reagent) to form a silver mirror, while ketones do not. Thus, B matches with IV.

Phenol reacts with neutral FeCl3FeCl_3 to form a violet-colored complex, whereas ethanol does not react. Thus, C matches with III.

Cinnamic acid contains a carbon-carbon double bond which decolorizes bromine water, whereas benzoic acid does not react with bromine water. Thus, D matches with I.

The correct matching is A-II, B-IV, C-III, D-I.

Answer: A-II, B-IV, C-III, D-I
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