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JEE Main 202623 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
23 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Amines

JEE Main 2026 · 23 January · Morning Shift · Chemistry · Amines

Compound ' P ' undergoes the following sequence of reactions : ' P^...

Compound ' P ' undergoes the following sequence of reactions :
Compound ' P ' undergoes the following sequence of reactions : ' P^ is :
' P′\mathrm{P}^{\prime} is :

Options

  1. AWhich of the following set is having correct statements here regarding both B and Al? 1. They combine with nitrogen to
  2. BWhich of the following set is having correct statements here regarding both B and Al? 1. They combine with nitrogen to
  3. CWhich of the following set is having correct statements here regarding both B and Al? 1. They combine with nitrogen to
  4. DWhich of the following set is having correct statements here regarding both B and Al? 1. They combine with nitrogen to

Correct answer

D. Which of the following set is having correct statements here regarding both B and Al? 1. They combine with nitrogen to

Step-by-step solution

The final product is cyclohexyl isocyanide (C6H11NCC_6H_{11}NC).
Working backwards from the final product:
The last step involves CHCl3CHCl_3 and KOHKOH (alc), which is the Carbylamine reaction.
This reaction converts a primary amine (R−NH2R-NH_2) into an isocyanide (R−NCR-NC). Thus, the intermediate before this step must be cyclohexylamine (C6H11NH2C_6H_{11}NH_2).
The step before cyclohexylamine involves Br2Br_2 and KOHKOH, which is the Hoffmann Bromamide Degradation reaction.
This reaction converts an amide (R−CONH2R-CONH_2) into a primary amine (R−NH2R-NH_2) with one less carbon atom.
Therefore, the amide 'Q' must be cyclohexanecarboxamide (C6H11CONH2C_6H_{11}CONH_2).
The first step converts 'P' into 'Q' using NH3NH_3 and heat.
Carboxylic acids react with NH3NH_3 followed by heating to form amides.
Thus, 'P' must be cyclohexanecarboxylic acid (C6H11COOHC_6H_{11}COOH).
Reaction sequence:
C6H11COOHC_6H_{11}COOH (P) →NH3,ΔC6H11CONH2\xrightarrow{NH_3, \Delta} C_6H_{11}CONH_2 (Q)
C6H11CONH2C_6H_{11}CONH_2 (Q) →Br2,KOHC6H11NH2\xrightarrow{Br_2, KOH} C_6H_{11}NH_2 (Cyclohexylamine)
C6H11NH2→CHCl3,KOHC6H11NCC_6H_{11}NH_2 \xrightarrow{CHCl_3, KOH} C_6H_{11}NC (Cyclohexyl isocyanide)
Comparing with the options, 'P' is cyclohexanecarboxylic acid, which corresponds to option (4).
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