JEE Main 202623 JanuaryMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 23 January
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Amines
JEE Main 2026 · 23 January · Morning Shift · Chemistry · Amines
Compound ' P ' undergoes the following sequence of reactions : ' P^...
Compound ' P ' undergoes the following sequence of reactions :
' is :
' is :
Options
- A

- B

- C

- D

Correct answer
D. 
Step-by-step solution
The final product is cyclohexyl isocyanide ().
Working backwards from the final product:
The last step involves and (alc), which is the Carbylamine reaction.
This reaction converts a primary amine () into an isocyanide (). Thus, the intermediate before this step must be cyclohexylamine ().
The step before cyclohexylamine involves and , which is the Hoffmann Bromamide Degradation reaction.
This reaction converts an amide () into a primary amine () with one less carbon atom.
Therefore, the amide 'Q' must be cyclohexanecarboxamide ().
The first step converts 'P' into 'Q' using and heat.
Carboxylic acids react with followed by heating to form amides.
Thus, 'P' must be cyclohexanecarboxylic acid ().
Reaction sequence:
(P) (Q)
(Q) (Cyclohexylamine)
(Cyclohexyl isocyanide)
Comparing with the options, 'P' is cyclohexanecarboxylic acid, which corresponds to option (4).
Working backwards from the final product:
The last step involves and (alc), which is the Carbylamine reaction.
This reaction converts a primary amine () into an isocyanide (). Thus, the intermediate before this step must be cyclohexylamine ().
The step before cyclohexylamine involves and , which is the Hoffmann Bromamide Degradation reaction.
This reaction converts an amide () into a primary amine () with one less carbon atom.
Therefore, the amide 'Q' must be cyclohexanecarboxamide ().
The first step converts 'P' into 'Q' using and heat.
Carboxylic acids react with followed by heating to form amides.
Thus, 'P' must be cyclohexanecarboxylic acid ().
Reaction sequence:
(P) (Q)
(Q) (Cyclohexylamine)
(Cyclohexyl isocyanide)
Comparing with the options, 'P' is cyclohexanecarboxylic acid, which corresponds to option (4).