JEE Main20241 Feb 2024Morning ShiftChemistryAminesActual
Given below are two statements: Statement (I) : The NH 2 group in Aniline is ortho and para directing and a powerful activating group. Statement (II) : Aniline does not undergo FriedelCraft's reaction (alkylation and acylation). In the light of the above statements, choose the most appropriate answer from the options given below:
Options
- ABoth Statement I and Statement II are correct
- BBoth Statement I and Statement II are incorrect
- CStatement I is incorrect but Statement II is correct
- DStatement I is correct but Statement II is incorrect
Correct answer
A. Both Statement I and Statement II are correct
Step-by-step solution
NH 2 is a highly activating group in organic chemistry due to its electron-donating nature. It is often used in synthetic chemistry to increase the reactivity of aromatic compounds towards electrophilic substitution reactions. Aniline forms salt with the Lewis acid catalyst i.e., AlCl 3 , which is used in Friedel-Crafts reaction. Nitrogen of aniline acquires a positive charge and hence acts as a strong deactivating group for further reaction. The NH 2 group in Aniline is ortho and para directing and a powerful acti