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JEE Main 202325 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
25 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Amines

JEE Main 2023 · 25 January · Evening Shift · Chemistry · Amines

Match List I with List II List I (Amines) List II (pKb) A. Aniline...

Match List I with List II

List I (Amines) List II (pKb)\left(pKb\right)
A. Aniline I. 3.253 . 25
B. Ethanamine II. 3.003 . 00
C. N-Ethylethanamine III. 9.389 . 38
D. N, N-Diethylethanamine IV. 3.293 . 29

Choose the correct answer from the options given below:-

Match List I with List II List I (Amines) List II (pKb) A. Aniline I. 3 . 25 B. Ethanamine II. 3 . 00 C.

Options

  1. AA-I, B-IV, C-II, D-III
  2. BA-III, B-II, C-I, D-IV
  3. CA-III, B-II, C-IV, D-I
  4. DA-III, B-IV, C-II, D-I

Correct answer

D. A-III, B-IV, C-II, D-I

Step-by-step solution

Among given aliphatic amines, 2° amine is most basic, followed by 3° amine and 1° amine.

Match List I with List II List I (Amines) List II (pKb) A. Aniline I. 3 . 25 B. Ethanamine II. 3 . 00 C.Therefore, the correct basic strength (Kb) order of the given amines is

(C) > (D) > (B) > (A)

The pKb order of the given amines will be just the opposite of their basic strength order.

The order is (A) > (B) > (D) > (C)

So the correct answer is A-III, B-IV, C-II, D-I

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