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JEE Main 202117 MarchMorning Shift
Exam
JEE Main
Year
2021
Date
17 March
Shift
Morning Shift
Subject
Chemistry
Chapter
Amines

JEE Main 2021 · 17 March · Morning Shift · Chemistry · Amines

Which of the following reaction is an example of ammonolysis?

Which of the following reaction is an example of ammonolysis?

Options

  1. AC6H5COCl+C6H5NH2⟶C6H5CONHC6H5{C}_{6}{H}_{5}COCl + {C}_{6}{H}_{5}{NH}_{2} ⟶ {C}_{6}{H}_{5}{CONHC}_{6}{H}_{5}
  2. BC6H5CH2CN⟶[H]C6H5CH2CH2NH2{C}_{6}{H}_{5}{CH}_{2}CN\overset{[ H ]}{⟶}{C}_{6}{H}_{5}{CH}_{2}{CH}_{2}{NH}_{2}
  3. CC6H5NH2⟶HClC6H5NH3Cl−{C}_{6}{H}_{5}{NH}_{2}\overset{HCl}{⟶}{C}_{6}{H}_{5}{NH}_{3}{Cl}^{-}
  4. DC6H5CH2Cl+NH3⟶C6H5CH2NH2{C}_{6}{H}_{5}{CH}_{2}Cl + {NH}_{3} ⟶ {C}_{6}{H}_{5}{CH}_{2}{NH}_{2}

Correct answer

D. C6H5CH2Cl+NH3⟶C6H5CH2NH2{C}_{6}{H}_{5}{CH}_{2}Cl + {NH}_{3} ⟶ {C}_{6}{H}_{5}{CH}_{2}{NH}_{2}

Step-by-step solution

The process of cleavage of the C−XC - X bond by Ammonia molecule is known as ammonolysis.

Ex:R−CH2−Cl+N¨H3⟶R−CH2−NH2Ex: R - {CH}_{2} - Cl + \overset{¨}{N}{H}_{3} ⟶ R - {CH}_{2} - {NH}_{2}

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