JEE Main20199 Jan 2019Evening ShiftChemistryAminesActual
The increasing basicity order of the following compounds is:
Options
- A( D ) < ( C ) < ( B ) < ( A )
- B( D ) < ( C ) < ( A ) < ( B )
- C( A ) < ( B ) < ( C ) < ( D )
- D( A ) < ( B ) < ( D ) < ( C )
Correct answer
B. ( D ) < ( C ) < ( A ) < ( B )
Step-by-step solution
In case of polar protic solvents, two factors decide the basic character. The positive inductive effect from alkyl groups which increases basicity. 3 o > 2 o > 1 o Amine & the Steric Hindrance. 1 o > 2   > 3 o  Thus, the resultant basic character is determined by taking the above two factors into account. So order will be 2 o > 1 o > 3 o if methyl group is present as alkyl group otherwise order will be 2 ° > 3 ° > 1 ° . In aromatic & Aliphatic: Aliphatic Amin