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JEE Main 20252 AprilMorning Shift
Exam
JEE Main
Year
2025
Date
2 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2025 · 2 April · Morning Shift · Chemistry · Classification of Elements and Periodicity in Properties

Given below are two statements : Statement (I): The metallic radius...

Given below are two statements :
Statement (I): The metallic radius of Al is less than that of Ga.
Statement (II) : The ionic radius of (\mathrm{Al}^{3+}) is less than that of (\mathrm{Ga}^{3+}).
In the light of the above statements, choose the most appropriate answer from the options given below :

Options

  1. ABoth Statement I and Statement II are incorrect
  2. BStatement I is incorrect but Statement II is correct
  3. CStatement I is correct but Statement II is incorrect
  4. DBoth Statement I and Statement II are correct

Correct answer

B. Statement I is incorrect but Statement II is correct

Step-by-step solution

(\Rightarrow) The metallic radius order of (Al\mathrm{Al}~\&~ Ga\mathrm{Ga}) is
(B<Ga<Al⏟↓<In<Tℓ\mathrm{B} \lt \underbrace{\mathrm{Ga} \lt \mathrm{Al}}_{\downarrow} \lt \mathrm{In} \lt \mathrm{T} \ell)
(due to poor shielding of d-subshell electrons)
(\Rightarrow) The ionic radius order of (Al+3\mathrm{Al}^{+3}~\&~ Ga+3\mathrm{Ga}^{+3}) is (\mathrm{B}^{+3} \lt Al+3<Ga+3<In+3<Tℓ+3\mathrm{Al}^{+3} \lt \mathrm{Ga}^{+3} \lt \mathrm{In}^{+3} \lt \mathrm{T} \ell^{+3})
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