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JEE Main 202331 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
31 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2023 · 31 January · Evening Shift · Chemistry · Classification of Elements and Periodicity in Properties

Given below are two statements: one is labelled as Assertion (A)...

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A): The first ionization enthalpy of 3d3d series elements is more than that of group 22 metals

Reason (R): In 3d3d series of elements successive filling of dd-orbitals takes place.

In the light of the above statements, choose the correct answer from the options given below:

Options

  1. ABoth (A) and (R) are true and (R) is the correct explanation of (A)
  2. B(A) is true but (R) is false
  3. C(A) is false but (R) is true
  4. DBoth (A) and (R) are true but (R) is not the correct explanation of (A)

Correct answer

A. Both (A) and (R) are true and (R) is the correct explanation of (A)

Step-by-step solution

Metal ScSc TiTi VV CrCr MnMn FeFe CoCo NiNi CuCu ZnZn
IE (kJ/mol)( kJ / mol ) 631631 656656 650650 653653 717717 762762 758758 736736 745745 906906
Metal BeBe MgMg CaCa SrSr BaBa RaRa
IE (kJ/mol)( kJ / mol ) 899899 737737 590590 549549 503503 509509

In the first transition series, the first and second ionization enthalpy values increase slowly on moving across the period. As the nuclear charge rises, the interaction between the nucleus and valence electrons increases, and as a result, the ionization enthalpy increases. So, Sc has the lowest value of ionization enthalpy while Zn has the highest value of ionization enthalpy.

So, both assertion and reasons are true and reason is the correct expalantion of assertion.

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