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JEE Main 202226 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
26 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2022 · 26 July · Morning Shift · Chemistry · Classification of Elements and Periodicity in Properties

Given two statements below : Statement I : In Cl _ 2 molecule the...

Given two statements below :

Statement I : In Cl2{Cl}_{2} molecule the covalent radius is double of the atomic radius of chlorine.

Statement II : Radius of anionic species is always greater than their parent atomic radius.

Choose the most appropriate answer from options given below

Options

  1. ABoth Statement I and Statement II are correct.
  2. BBoth Statement I and Statement II are incorrect.
  3. CStatement I is correct but Statement II is incorrect.
  4. DStatement I is incorrect but Statement II is correct.

Correct answer

D. Statement I is incorrect but Statement II is correct.

Step-by-step solution

In Cl2{Cl}_{2} molecule, the covalent radius is half of the internuclear distance, so statement (I)\left(I\right) is false. The covalent radius is little smaller than the actual radius of the atom of chlorine due to overlapping during formation of covalent bond.

For the same element, anion has lower effective nuclear charge than atom so, anion is larger than the parent atom. That means statement (II)\left(II\right) is correct.

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