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JEE Main 202225 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
25 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2022 · 25 July · Evening Shift · Chemistry · Classification of Elements and Periodicity in Properties

The first ionization enthalpies of Be, B, N and O follow the order

The first ionization enthalpies of Be,B,NBe, B, N and OO follow the order

Options

  1. AB<Be<O<NB < Be < O < N
  2. BO<N<B<BeO < N < B < Be
  3. CBe<B<N<OBe < B < N < O
  4. DB<Be<N<OB < Be < N < O

Correct answer

A. B<Be<O<NB < Be < O < N

Step-by-step solution

The ionisation enthalpy increases as we go from left to right in a period, while it decreases as we come down a group. So according to this, the order will be Be<B<C<N<OBe < B < C < N < O. But there are two exceptions, in the case of BeBe and NN because of the highly stable 2s22{s}^{2} (completely filled orbital)and2s22p3and 2{s}^{2}2{p}^{3} (half-filled orbital 2p32{p}^{3}) valence configuration. Due to this, the correct order is:
B<Be<C<O<NB < Be < C < O < N.

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