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JEE Main 20207 JanuaryEvening Shift
Exam
JEE Main
Year
2020
Date
7 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2020 · 7 January · Evening Shift · Chemistry · Classification of Elements and Periodicity in Properties

Within each pair of elements F and~ Cl , S and~ Se , and Li and~ Na...

Within each pair of elements FF and~ClCl , SS and~SeSe , and Li\text{Li}and~NaNa , respectively, the elements that release more energy upon an electron gain are

Options

  1. ACl,SeCl, Se and NaNa
  2. BCl,SCl, S and LiLi
  3. CF,SF, S and LiLi
  4. DF,SeF, Se and NaNa

Correct answer

B. Cl,SCl, S and LiLi

Step-by-step solution

(i) Electron affinity of second period pp-block element is less than third period pp-block element due to small size of second period pp-block element, due to small size electron density is more and upcoming electron face extra repulsion, so energy release is less. Hence, EA order: F<ClF < Cl.

(ii) Down the group electron affinity decreases due to size increases. EA order: S>SeLi>NaS > SeLi > Na.
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