JEE Main20207 Jan 2020Morning ShiftChemistryClassification of Elements and Periodicity in PropertiesActual
The electron gain enthalpy (in kJ m o l ) of fluorine, chlorine, bromine and iodine, respectively, are
Options
- A- 296 , - 325 , - 333 and - 349
- B- 349 , - 333 , - 325 and - 296
- C- 333 , - 349 , - 325 and - 296
- D- 333 , - 325 , - 349 and - 296
Correct answer
C. - 333 , - 349 , - 325 and - 296
Step-by-step solution
Order of electron gain enthalpy Cl > F > Br > I Electron gain enthalpy of third period elements are greater than second period elements. Electron gain enthalpy decrease down to the group, but here Electron gain enthalpy of chlorine is greater than fluorine, it is due to small size of fluorine atom, due to which electron density is high than chlorine, hence upcoming electron face high repulsion in F atom, hence the energy released is less than chlorine.