JEE Main 202622 JanuaryEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 22 January
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Coordination Compounds
JEE Main 2026 · 22 January · Evening Shift · Chemistry · Coordination Compounds
[Ni (PPh_ 3 )_ 2 Cl_ 2 ] is a paramagnetic complex. Identify the...
\left[\mathrm{Ni}\left(\mathrm{PPh}_{3}\right)_{2} \mathrm{Cl}_{2}\right] is a paramagnetic complex. Identify the INCORRECT statements about this complex.
A. The complex exhibits geometrical isomerism.
B. The complex is white in colour.
C. The calculated spin-only magnetic moment of the complex is 2.84 BM .
D. The calculated CFSE (Crystal Field Stabilization Energy) of Ni in this complex is .
E. The geometrical arrangement of ligands in this complex is similar to that in .
Choose the correct answer from the options given below :
A. The complex exhibits geometrical isomerism.
B. The complex is white in colour.
C. The calculated spin-only magnetic moment of the complex is 2.84 BM .
D. The calculated CFSE (Crystal Field Stabilization Energy) of Ni in this complex is .
E. The geometrical arrangement of ligands in this complex is similar to that in .
Choose the correct answer from the options given below :
Options
- AC, D and E Only
- BC and D Only
- CA, B and D Only
- DA and B Only
Correct answer
C. A, B and D Only
Step-by-step solution
In , Nickel is in oxidation state. has a electronic configuration.
The complex is given as paramagnetic. For a 4-coordinate system, paramagnetism implies a tetrahedral geometry ( hybridization) with two unpaired electrons.
Statement A: Tetrahedral complexes of the type do not exhibit geometrical isomerism because all positions are adjacent to each other. Thus, A is incorrect.
Statement B: Most complexes are colored due to transitions. is a dark blue/green crystalline solid, not white. Thus, B is incorrect.
Statement C: With 2 unpaired electrons, the spin-only magnetic moment BM. Thus, C is correct.
Statement D: For a tetrahedral complex with configuration, the CFSE is calculated as . The statement mentions , which is incorrect as the complex is tetrahedral, not octahedral. Thus, D is incorrect.
Statement E: is a tetrahedral complex ( hybridization). Since is also tetrahedral, their geometrical arrangements are similar. Thus, E is correct.
The incorrect statements are A, B, and D.
The complex is given as paramagnetic. For a 4-coordinate system, paramagnetism implies a tetrahedral geometry ( hybridization) with two unpaired electrons.
Statement A: Tetrahedral complexes of the type do not exhibit geometrical isomerism because all positions are adjacent to each other. Thus, A is incorrect.
Statement B: Most complexes are colored due to transitions. is a dark blue/green crystalline solid, not white. Thus, B is incorrect.
Statement C: With 2 unpaired electrons, the spin-only magnetic moment BM. Thus, C is correct.
Statement D: For a tetrahedral complex with configuration, the CFSE is calculated as . The statement mentions , which is incorrect as the complex is tetrahedral, not octahedral. Thus, D is incorrect.
Statement E: is a tetrahedral complex ( hybridization). Since is also tetrahedral, their geometrical arrangements are similar. Thus, E is correct.
The incorrect statements are A, B, and D.