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JEE Main 202622 JanuaryEvening Shift
Exam
JEE Main
Year
2026
Date
22 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Coordination Compounds

JEE Main 2026 · 22 January · Evening Shift · Chemistry · Coordination Compounds

[Ni (PPh_ 3 )_ 2 Cl_ 2 ] is a paramagnetic complex. Identify the...

\left[\mathrm{Ni}\left(\mathrm{PPh}_{3}\right)_{2} \mathrm{Cl}_{2}\right] is a paramagnetic complex. Identify the INCORRECT statements about this complex.
A. The complex exhibits geometrical isomerism.
B. The complex is white in colour.
C. The calculated spin-only magnetic moment of the complex is 2.84 BM .
D. The calculated CFSE (Crystal Field Stabilization Energy) of Ni in this complex is −0.8Δo-0.8 \Delta_{\mathrm{o}}.
E. The geometrical arrangement of ligands in this complex is similar to that in Ni(CO)4\mathrm{Ni}(\mathrm{CO})_{4}.
Choose the correct answer from the options given below :

Options

  1. AC, D and E Only
  2. BC and D Only
  3. CA, B and D Only
  4. DA and B Only

Correct answer

C. A, B and D Only

Step-by-step solution

In [Ni(PPh3)2Cl2][Ni(PPh_3)_2Cl_2], Nickel is in +2+2 oxidation state. Ni2+Ni^{2+} has a 3d83d^8 electronic configuration.
The complex is given as paramagnetic. For a 4-coordinate d8d^8 system, paramagnetism implies a tetrahedral geometry (sp3sp^3 hybridization) with two unpaired electrons.
Statement A: Tetrahedral complexes of the type [MA2B2][MA_2B_2] do not exhibit geometrical isomerism because all positions are adjacent to each other. Thus, A is incorrect.
Statement B: Most Ni(II)Ni(II) complexes are colored due to d−dd-d transitions. [Ni(PPh3)2Cl2][Ni(PPh_3)_2Cl_2] is a dark blue/green crystalline solid, not white. Thus, B is incorrect.
Statement C: With 2 unpaired electrons, the spin-only magnetic moment μ=n(n+2)=2(2+2)=8≈2.83\mu = \sqrt{n(n+2)} = \sqrt{2(2+2)} = \sqrt{8} \approx 2.83 BM. Thus, C is correct.
Statement D: For a tetrahedral complex with d8d^8 configuration, the CFSE is calculated as CFSE=[(−0.6×4)+(0.4×4)]Δt=−0.8ΔtCFSE = [(-0.6 \times 4) + (0.4 \times 4)]\Delta_t = -0.8\Delta_t. The statement mentions −0.8Δo-0.8\Delta_o, which is incorrect as the complex is tetrahedral, not octahedral. Thus, D is incorrect.
Statement E: Ni(CO)4Ni(CO)_4 is a tetrahedral complex (sp3sp^3 hybridization). Since [Ni(PPh3)2Cl2][Ni(PPh_3)_2Cl_2] is also tetrahedral, their geometrical arrangements are similar. Thus, E is correct.
The incorrect statements are A, B, and D.
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