JEE Main 202622 JanuaryMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 22 January
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Coordination Compounds
JEE Main 2026 · 22 January · Morning Shift · Chemistry · Coordination Compounds
Consider the transition metal ions Mn^ 3+ , Cr^ 3+ , Fe^ 3+ and Co^...
Consider the transition metal ions and and all form low spin octahedral complexes. The correct decreasing order of unpaired electrons in their respective d-orbitals of the complexes is
Options
- A
- B
- C
- D
Correct answer
B.
Step-by-step solution
For low spin octahedral complexes, electrons fill the orbitals first before pairing or moving to orbitals. The configuration depends on the number of d-electrons.
For : Electronic configuration is . In an octahedral field, the configuration is . Number of unpaired electrons () = 3.
For : Electronic configuration is . For low spin, the configuration is . Number of unpaired electrons () = 2.
For : Electronic configuration is . For low spin, the configuration is . Number of unpaired electrons () = 1.
For : Electronic configuration is . For low spin, the configuration is . Number of unpaired electrons () = 0.
Comparing the number of unpaired electrons:
.
The correct decreasing order is .
For : Electronic configuration is . In an octahedral field, the configuration is . Number of unpaired electrons () = 3.
For : Electronic configuration is . For low spin, the configuration is . Number of unpaired electrons () = 2.
For : Electronic configuration is . For low spin, the configuration is . Number of unpaired electrons () = 1.
For : Electronic configuration is . For low spin, the configuration is . Number of unpaired electrons () = 0.
Comparing the number of unpaired electrons:
.
The correct decreasing order is .