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JEE Main 202622 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
22 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Coordination Compounds

JEE Main 2026 · 22 January · Morning Shift · Chemistry · Coordination Compounds

Consider the transition metal ions Mn^ 3+ , Cr^ 3+ , Fe^ 3+ and Co^...

Consider the transition metal ions Mn3+,Cr3+,Fe3+\mathrm{Mn}^{3+}, \mathrm{Cr}^{3+}, \mathrm{Fe}^{3+} and Co3+\mathrm{Co}^{3+} and all form low spin octahedral complexes. The correct decreasing order of unpaired electrons in their respective d-orbitals of the complexes is

Options

  1. AMn3+>Fe3+>Co3+>Cr3+\mathrm{Mn}^{3+}>\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}>\mathrm{Cr}^{3+}
  2. BCr3+>Mn3+>Fe3+>Co3+\mathrm{Cr}^{3+}>\mathrm{Mn}^{3+}>\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}
  3. CFe3+>Co3+>Mn3+>Cr3+\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}>\mathrm{Mn}^{3+}>\mathrm{Cr}^{3+}
  4. DCr3+>Fe3+>Co3+>Mn3+\mathrm{Cr}^{3+}>\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}>\mathrm{Mn}^{3+}

Correct answer

B. Cr3+>Mn3+>Fe3+>Co3+\mathrm{Cr}^{3+}>\mathrm{Mn}^{3+}>\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}

Step-by-step solution

For low spin octahedral complexes, electrons fill the t2gt_{2g} orbitals first before pairing or moving to ege_g orbitals. The configuration depends on the number of d-electrons.
For Cr3+Cr^{3+}: Electronic configuration is 3d33d^3. In an octahedral field, the configuration is t2g3eg0t_{2g}^3 e_g^0. Number of unpaired electrons (nn) = 3.
For Mn3+Mn^{3+}: Electronic configuration is 3d43d^4. For low spin, the configuration is t2g4eg0t_{2g}^4 e_g^0. Number of unpaired electrons (nn) = 2.
For Fe3+Fe^{3+}: Electronic configuration is 3d53d^5. For low spin, the configuration is t2g5eg0t_{2g}^5 e_g^0. Number of unpaired electrons (nn) = 1.
For Co3+Co^{3+}: Electronic configuration is 3d63d^6. For low spin, the configuration is t2g6eg0t_{2g}^6 e_g^0. Number of unpaired electrons (nn) = 0.
Comparing the number of unpaired electrons:
Cr3+(3)>Mn3+(2)>Fe3+(1)>Co3+(0)Cr^{3+} (3) > Mn^{3+} (2) > Fe^{3+} (1) > Co^{3+} (0).
The correct decreasing order is Cr3+>Mn3+>Fe3+>Co3+Cr^{3+} > Mn^{3+} > Fe^{3+} > Co^{3+}.
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