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JEE Main 202524 JanuaryEvening Shift
Exam
JEE Main
Year
2025
Date
24 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Coordination Compounds

JEE Main 2025 · 24 January · Evening Shift · Chemistry · Coordination Compounds

The conditions and consequence that favours the t_ 2 g ^3 e_g^1...

The conditions and consequence that favours the t2g3eg1t_{2 g}^3 e_g^1 configuration in a metal complex are

Options

  1. Aweak field ligand, low spin complex
  2. Bweak field ligand, high spin complex
  3. Cstrong field ligand, high spin complex
  4. Dstrong field ligand, low spin complex

Correct answer

B. weak field ligand, high spin complex

Step-by-step solution

The conditions and consequence that favour t2g3eg1t_{2 g}^3 e_g^1 configuration in a metal complex are (i) weak field ligand, and (ii) high spin complex For weak field ligands, splitting energy ( Δ0\Delta_0 ) is lower than pairing energy (P)(P). As a result distribution of electrons for 3 d43 \mathrm{~d}^4 will be t2 g3eg1t_{2 \mathrm{~g}}^3 \mathrm{e}_{\mathrm{g}}^1. It results in high spin complex due to maximum number of unpaired electrons.
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