- Exam
- JEE Main
- Year
- 2024
- Date
- 29 January
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- d and f Block Elements
JEE Main 2024 · 29 January · Evening Shift · Chemistry · d and f Block Elements
Which of the following statements are correct about Zn, Cd and Hg ?...
A. They exhibit high enthalpy of atomization as the d-subshell is full.
B. and do not show variable oxidation state while shows and .
C. Compounds of and are paramagnetic in nature.
D. and are called soft metals.
Choose the most appropriate from the options given below:
Options
- AB, D only
- BB, C only
- CA, D only
- DC, D only
Correct answer
A. B, D only
Step-by-step solution
(A) and have low values of enthalpies of atomization. These metals have relatively weak metallic bonding due to their filled or nearly filled d-orbitals. In these metals, the valence electrons are not as delocalized as in other transition metals because the d-orbitals are filled or nearly filled. This leads to weaker metallic bonding, resulting in lower enthalpies compared to transition metals with partially filled d-orbitals. Thus statement (A) is incorrect.
(B) and shows oxidation state whereas shows and oxidation state.Hence, statement (B) is correct.
(C) All electrons are paired in the compounds of zinc, cadmium and mercury. Hence, they are diamagnetic in nature. Hence, statement (C) is incorrect.
(D) and are soft metals as all electrons are paired and metallic bonds are not strong enough. Thus, statement (D) is correct.