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JEE Main 202429 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
29 January
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 29 January · Evening Shift · Chemistry · d and f Block Elements

Which of the following statements are correct about Zn, Cd and Hg ?...

Which of the following statements are correct about Zn,CdZn, Cd and HgHg ?
A. They exhibit high enthalpy of atomization as the d-subshell is full.
B. ZnZn and CdCd do not show variable oxidation state while HgHg shows +I+ I and +II+ II.
C. Compounds of Zn,CdZn, Cd and HgHg are paramagnetic in nature.
D. Zn,CdZn, Cd and HgHg are called soft metals.
Choose the most appropriate from the options given below:

Options

  1. AB, D only
  2. BB, C only
  3. CA, D only
  4. DC, D only

Correct answer

A. B, D only

Step-by-step solution

(A) Zn,CdZn, Cd and HgHg have low values of enthalpies of atomization. These metals have relatively weak metallic bonding due to their filled or nearly filled d-orbitals. In these metals, the valence electrons are not as delocalized as in other transition metals because the d-orbitals are filled or nearly filled. This leads to weaker metallic bonding, resulting in lower enthalpies compared to transition metals with partially filled d-orbitals. Thus statement (A) is incorrect.
(B) ZnZn and CdCd shows +2+ 2 oxidation state whereas HgHg shows +1+ 1 and +2+ 2 oxidation state.Hence, statement (B) is correct.
(C) All electrons are paired in the compounds of zinc, cadmium and mercury. Hence, they are diamagnetic in nature. Hence, statement (C) is incorrect.
(D) Zn,CdZn, Cd and HgHg are soft metals as all electrons are paired and metallic bonds are not strong enough. Thus, statement (D) is correct.

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