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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

NTA Abhyas 2020 · Chemistry · p Block Elements (Group 13 & 14)

NaB H _ 4 + I _ 2 → X + Y + Z BF_ 3 + LiAlH_ 4 450K → X+P B F _ 3 +...

NaBH4+I2→X+Y+ZNaB{H}_{4} + {I}_{2} \to X + Y + Z
{\text{BF}_{3} \text{+}{\text{LiAlH}_{4} \overset{\text{450}\text{K}}{→} \text{X}\text{+}\text{P}
BF3+LiAlH4→X+Q+RB{F}_{3} + LiAl{H}_{4} \to X + Q + R

X, Y, Z, P, Q and R in the reactions are

Options

  1. A
    X Y Z P Q R
    Na4B4O7N{a}_{4}{B}_{4}{O}_{7} NaI HI HF AlF3{AlF}_{3} LiF
  2. B
    X Y Z P Q R
    B2H6{B}_{2}{H}_{6} NaI H2{H}_{2} NaF LiFLiF AlF3{AlF}_{3}
  3. C
    X Y Z P Q R
    B2H6{B}_{2}{H}_{6} BH3B{H}_{3} NaI B3N3H6{B}_{3}{N}_{3}{H}_{6} A{l}_{2}{F}_{6}</td><td></td> <td>Al{F}_{3}</td></tr></tbody></table></td> </tr> </tbody></table>
  4. D
    X Y Z P Q R
    BH3B{H}_{3} B2H6{B}_{2}{H}_{6} H2{H}_{2} B3N3H6{B}_{3}{N}_{3}{H}_{6} LiF AlF3Al{F}_{3}
  5. Correct answer

    B.

    X Y Z P Q R
    B2H6{B}_{2}{H}_{6} NaI H2{H}_{2} NaF LiFLiF AlF3{AlF}_{3}

    Step-by-step solution

    2NaBH4+I2→B2H6(X)+2NaI(Y)+H2(Z)2NaB{H}_{4} + {I}_{2} \to \mathop{{B}_{2}{H}_{6}}_{( X )} + \mathop{2NaI}_{( Y )} + \mathop{{H}_{2}}_{( Z )}
    {\text{2BF}_{3} \text{+}\text{6NaH}\overset{\text{450}\text{K}}{→} \mathop{{B}_{2} {H}_{6}}_{\left(\text{X}\right)} \text{+}\mathop{\text{6NaF}_{\left(\text{P}\right)}
    4BF3+3LiAlH4→2B2H6(X)+3LiF(Q)+3AlF3(R)4B{F}_{3} + 3LiAl{H}_{4} \to \mathop{2{B}_{2}{H}_{6}}_{( X )} + \mathop{3LiF}_{( Q )} + \mathop{3Al{F}_{3}}_{( R )}
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