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JEE Advanced 2023Paper 2
Exam
JEE Advanced
Year
2023
Paper
Paper 2
Subject
Chemistry
Chapter
Coordination Compounds

JEE Advanced 2023 · Paper 2 · Chemistry · Coordination Compounds

The complex(es), which can exhibit the type of isomerism shown by...

The complex(es), which can exhibit the type of isomerism shown by \left[Pt{\left({NH}_{3}\right)}_{2}{Br}_{2}\right],is(are)[en=H2NCH2CH2NH2]</p><p>, is(are) \left[en = {H}_{2}{NCH}_{2}{CH}_{2}{NH}_{2}\right]</p><p>

Options

  1. A[Pt(en)(SCN)2]\left[Pt ( en ) ( SCN{)}_{2}\right]
  2. B[Zn(NH3)2Cl2]\left[Zn{\left({NH}_{3}\right)}_{2}{Cl}_{2}\right]
  3. C[Pt(NH3)2Cl4]\left[Pt{\left({NH}_{3}\right)}_{2}{Cl}_{4}\right]
  4. D[ Cr ( en )2(H2O)(SO4)]+{\left[\text{ Cr } (\text{ en }{)}_{2}\left({H}_{2}O\right)\left({SO}_{4}\right)\right]}^{+}

Correct answer

C. [Pt(NH3)2Cl4]\left[Pt{\left({NH}_{3}\right)}_{2}{Cl}_{4}\right]

Step-by-step solution

\left[Pt{\left({NH}_{3}\right)}_{2}{Cl}_{2}\right]is a square planar complex and itcanexhibitgeometricalisomerism.Ithastwoisomers,cis−platinandtrans−platin.Thecomplexesit can exhibit geometrical isomerism. It has two isomers, cis-platin and trans-platin. The complexes\left[Zn{(NH3)\left({NH}_{3}\right)}_{2}{Cl}_{2}\right]\left(tetrahedral\right)andand\left[Pt ( en ) ( SCN{)}_{2}\right]doesnotexhibitgeometricalisomerism.Theoctahedralcomplexdoes not exhibit geometrical isomerism. The octahedral complex\left[Pt{(NH3)\left({NH}_{3}\right)}_{2}{Cl}_{4}\right]showsgeometricalisomerism,ithastwogeometricalisomerscisandtrans.</p><p>shows geometrical isomerism, it has two geometrical isomers cis and trans.</p><p>{\left[Cr ( en{)}_{2}(H2O)(SO4)\left({H}_{2}O\right)\left({SO}_{4}\right)\right]}^{+} is an octahedral complex, it is of the type M(AA)M{\left(AA\right)}_{2}bcanditcanexhibitthegeometricalisomerism.</p>and it can exhibit the geometrical isomerism.</p>

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