JEE Main 202624 JanuaryMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 24 January
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Amines
JEE Main 2026 · 24 January · Morning Shift · Chemistry · Amines
The correct stability order of the following diazonium salts is
The correct stability order of the following diazonium salts is

Options
- A
- B
- C
- D
Correct answer
B.
Step-by-step solution
The stability of benzenediazonium salts is governed by the electronic effects of the substituents present on the benzene ring.
The diazonium group is strongly electron-withdrawing. Electron-donating groups (EDG) stabilize the diazonium cation by dispersing the positive charge through resonance or inductive effects, whereas electron-withdrawing groups (EWG) destabilize it by increasing the positive charge density.
In (A), the group at the para position is a strong electron-donating group via the effect, which significantly stabilizes the diazonium ion.
In (C), there is no substituent (hydrogen), providing a baseline stability.
In (D), the group is an electron-withdrawing group via and effects, which destabilizes the cation.
In (B), the group is a very strong electron-withdrawing group via and effects, even stronger than , leading to the least stability.
Comparing the effects: of (A) > (C) > of (D) > of (B).
Therefore, the correct stability order is .
The diazonium group is strongly electron-withdrawing. Electron-donating groups (EDG) stabilize the diazonium cation by dispersing the positive charge through resonance or inductive effects, whereas electron-withdrawing groups (EWG) destabilize it by increasing the positive charge density.
In (A), the group at the para position is a strong electron-donating group via the effect, which significantly stabilizes the diazonium ion.
In (C), there is no substituent (hydrogen), providing a baseline stability.
In (D), the group is an electron-withdrawing group via and effects, which destabilizes the cation.
In (B), the group is a very strong electron-withdrawing group via and effects, even stronger than , leading to the least stability.
Comparing the effects: of (A) > (C) > of (D) > of (B).
Therefore, the correct stability order is .