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JEE Main 202621 JanuaryEvening Shift
Exam
JEE Main
Year
2026
Date
21 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Amines

JEE Main 2026 · 21 January · Evening Shift · Chemistry · Amines

Consider the above sequence of reactions. The number of bromine...

Consider the above sequence of reactions. The number of bromine atom(s) in the final product (P) will be :
Consider the above sequence of reactions. The number of bromine atom(s) in the final product (P) will be :

Options

  1. A3
  2. B5
  3. C6
  4. D1

Correct answer

B. 5

Step-by-step solution

The reaction sequence is as follows:
1. Bromination of nitrobenzene with Br2/FeBr3Br_2/FeBr_3 results in meta-bromonitrobenzene because the −NO2-NO_2 group is meta-directing. (1 Br atom)
2. Reduction of the nitro group using Sn/HClSn/HCl followed by pH neutralization converts −NO2-NO_2 to −NH2-NH_2. The product is m-bromoaniline.
3. Reaction with Br2/H2OBr_2/H_2O (bromine water) on m-bromoaniline: The −NH2-NH_2 group is highly activating and ortho/para directing. In m-bromoaniline, the positions ortho and para to −NH2-NH_2 are vacant (positions 2, 4, and 6 relative to −NH2-NH_2). Bromine water causes polybromination at all available ortho and para positions. This adds 3 more bromine atoms. (Total 1 + 3 = 4 Br atoms)
4. Diazotization with NaNO2/HBrNaNO_2/HBr at 0−5∘C0-5^{\circ}C converts the −NH2-NH_2 group into a diazonium salt −N2+Br−-N_2^+Br^-.
5. Sandmeyer reaction with CuBr/NaBrCuBr/NaBr replaces the diazonium group with a bromine atom. (Total 4 + 1 = 5 Br atoms)
The final product (P) is 1,2,3,4,5-pentabromobenzene. Therefore, the number of bromine atoms in the final product is 5.
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