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JEE Main 20244 AprilMorning Shift
Exam
JEE Main
Year
2024
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Amines

JEE Main 2024 · 4 April · Morning Shift · Chemistry · Amines

(X g) of ethylamine is subjected to reaction with (NaNO_2 / HCl)...

(\mathrm{X} \mathrm{g}) of ethylamine is subjected to reaction with (\mathrm{NaNO}_2 / \mathrm{HCl}) followed by water; evolved dinitrogen gas which occupied (2.24 \mathrm{~L}) volume at STP. (\mathrm{X}) is (\qquad) (\times 10^{-1} \mathrm{~g}).

Correct answer

45

Step-by-step solution

CH3CH2NH2 Mol.wt.45g →NaNO2+HCl→H2OCH3CH2−OH+ N214 g\underset{\substack{\text{ Mol.wt.45g }}}{\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2} \xrightarrow{\mathrm{NaNO}_2+\mathrm{HCl}} \xrightarrow{\mathrm{H}_2 \mathrm{O}} \mathrm{CH}_3 \mathrm{CH}_2-\mathrm{OH}+\underset{14 \mathrm{~g}}{\mathrm{~N}_2} given : N2\mathrm{N}_2 evolved is 2.24 L i.e. 0.1 mole. i.e. CH3CH2NH2\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2 (ethyl amine) will be 4.5 g(=0.1 mole)4.5 \mathrm{~g}(=0.1 \mathrm{~mole}) Hence the answer =45×10−1 g=45 \times 10^{-1} \mathrm{~g}
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