Match List-I with List-II List-I List-II A Benzenesulphonyl...

Benzen sulphonyl chloride

(B) Hoffmann bromamide reaction $\to$known reaction of isocynates

$R - CO - {NH}_{2} + {X}_{2} + 4NaOH \to R - {NH}_{2} + 2NaX + {Na}_{2}{CO}_{3} + 2{H}_{2}O$

Intermediate : $R - N = C = O$ (isocyanate)

(C) Carbylamine reaction $\to$ Test for primary amine
$R - {NH}_{2}$ or $Ar - {NH}_{2} + {CHCl}_{3} + 3KOH \to RNC$

(D) Hoffmann orientation $\to$ Anti saytzeff (Formation of less substituted alkene as major product)