JEE Main 202325 JanuaryEvening Shift
- Exam
- JEE Main
- Year
- 2023
- Date
- 25 January
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Coordination Compounds
JEE Main 2023 · 25 January · Evening Shift · Chemistry · Coordination Compounds
Total number of moles of AgCl precipitated on addition of excess of...
Total number of moles of AgCl precipitated on addition of excess of to one mole each of the following complexes \left[Co{\left({NH}_{3}\right)}_{4}{Cl}_{2}\right]Cl, \left[Ni{\left({H}_{2}O\right)}_{6}\right]{Cl}_{2}, \left[Pt{\left({NH}_{3}\right)}_{2}{Cl}_{2}\right]and \left[Pd{\left({\text{ NH }}_{3}\right)}_{4}\right]{Cl}_{2} is
Correct answer
5
Step-by-step solution
Silver nitrate on reaction of chloride ion gives silver chloride as precipitate. Chloride ions outside of coordination sphere will only give precipitates. Thus,
Gives mole
\left[Ni{\left({H}_{2}O\right)}_{6}\right]{Cl}_{2} ⇒2AgCl Gives No
\left[Pd{\left({NH}_{3}\right)}_{4}\right]{Cl}_{2} ⇒2AgClAgCl = 5 mole.
Gives mole
\left[Ni{\left({H}_{2}O\right)}_{6}\right]{Cl}_{2} ⇒2AgCl Gives No
\left[Pd{\left({NH}_{3}\right)}_{4}\right]{Cl}_{2} ⇒2AgClAgCl = 5 mole.